N,N '-bis(2-tosylaminobenzylidene)-1,3-propanediamine

Citation
J. Mahia et al., N,N '-bis(2-tosylaminobenzylidene)-1,3-propanediamine, ACT CRYST C, 55, 1999, pp. 1545-1547
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS
ISSN journal
01082701 → ACNP
Volume
55
Year of publication
1999
Part
9
Pages
1545 - 1547
Database
ISI
SICI code
0108-2701(19990915)55:<1545:N'>2.0.ZU;2-W
Abstract
The conformation of the title molecule, C(31)H(32)N(4)O(4)S2(,) in the soli d state is strongly influenced by intramolecular hydrogen-bond interactions (N-H ... N), which probably minimize the steric hindrance of the tosyl gro ups. The molecule is not planar and with long distances between aminic N at oms [7.724(3) Angstrom], a major change in conformation will be required fo r it to act as a tecradentate ligand via its four N atoms.