Fd. Rochon et L. Breau, (+)-(2S,7R,9R,10S)-2-ethenyl-4,4,7-trimethyl-3-(toluene-4-sulfonyl)-3,4,4a,5,6,7,8,8a-octahydro-2H-1,3-benzoxazine, ACT CRYST C, 55, 1999, pp. 1587-1589
The title compound, C20H29NO3S, was studied in order to determine its absol
ute configuration, which could not be determined unambiguously by NMR techn
iques. The results have shown a boat conformation for the oxazine moiety, w
ith S stereochemistry at the stereocentre bearing the alkene function.