M. Likon et al., MOLECULAR-WEIGHT DISTRIBUTION STUDY OF DELIGNIFICATION OF SPRUCE WOODMEAL WITH CHLOROACETIC ACIDS, Journal of wood chemistry and technology, 17(1-2), 1997, pp. 135-146
The amount of lignin removed from spruce wood meal at 50 degrees C to
110 degrees C with mono-, di-, and trichloroacetic acid, as well as it
s molecular weight (MW) distribution was studied. Trichloroacetic acid
gives rise to the lowest M-n (2,000-4,000), the lowest M-W (4,500-8,0
00), the lowest upper MW limit (similar to 40,000), and the lowest pol
ydispersity(1.5-3.0) of lignin. The removed lignin is split by the tes
ted acids to different extents.