Reactive intermediates from carbonylation of ruthenium(I) carbonyl carboxylates. Isolation, molecular structures and chemical properties of dinuclearunbridged ruthenium carbonyl trifluoroacetates

Authors
Funaioli, T Marchetti, F Fachinetti, G
Citation
T. Funaioli et al., Reactive intermediates from carbonylation of ruthenium(I) carbonyl carboxylates. Isolation, molecular structures and chemical properties of dinuclearunbridged ruthenium carbonyl trifluoroacetates, CHEM COMMUN, (20), 1999, pp. 2043-2044
Citations number
19
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
20
Year of publication
1999
Pages
2043 - 2044
Database
ISI
SICI code
1359-7345(1999):20<2043:RIFCOR>2.0.ZU;2-Q
Abstract
Carboxylato-bridged Ru(I) carbonyl complexes are activated by CO towards bo th disproportionation and reaction with dihydrogen, through the intermediac y of the unbridged metal-metal bonded valence isomers (OC)(5)RuRu(CO)(3)- ( OCOCR3)(2) and [Ru(CO)(4)(OCOCR3)](2).