Application of a new modification of the radical-freezing-out technique tostudying elementary gas-phase reactions. Reaction HO2+NO=OH+NO2

Authors
Gershenzon, YM Il'in, SD Politenkova, GG Remorov, RG
Citation
Ym. Gershenzon et al., Application of a new modification of the radical-freezing-out technique tostudying elementary gas-phase reactions. Reaction HO2+NO=OH+NO2, CHEM PHYS R, 18(1), 1999, pp. 91-101
Citations number
12
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS REPORTS
ISSN journal
10741550 → ACNP
Volume
18
Issue
1
Year of publication
1999
Pages
91 - 101
Database
ISI
SICI code
1074-1550(1999)18:1<91:AOANMO>2.0.ZU;2-P
Abstract
Freezing-cut of radicals (RFT) with subsequent recording of their spin reso nance spectrum is applied for the first time to studies of a fast gas-phase reaction HO2 + NO = OH + NO2. The rate constant determined at T = 295 K eq uals (7.3 +/- 2) . 10(-12) cm(3)/s and is close to the value recommended in the literature of (8.6 +/- 1.7) . 10(-12) cm(3)/s. The RFT modification su ggested previously was employed to study this fast elementary gas-phase rea ction.