T. Kasamatsu et al., FORMATION OF ORGANIC-COMPOUNDS IN SIMULATED INTERSTELLAR MEDIA WITH HIGH-ENERGY PARTICLES, Bulletin of the Chemical Society of Japan, 70(5), 1997, pp. 1021-1026
Abiotic formation of amino acid precursors in interstellar dusts (ISDs
) by cosmic radiation was quantitatively examined. In order to study t
he formation of organic compounds in ISDs, ice mixtures of carbon mono
xide (or methane), ammonia, and water made in a cryostat at 10 K were
irradiated with high energy protons. Irradiated ice products were warm
ed up to room temperature, while sublimed gases were analyzed with a q
uadrupole mass spectrometer. Some hydrocarbons and alcohols were detec
ted. Amino acid precursors, which gave amino acids after acid-hydrolys
is, were detected in non-volatile products remaining on the substrate
at room temperature. G-values of glycine precursors from methanol, amm
onia, and water in solid state irradiation were about 6x10(-4), which
was about two orders less than those in gasous state irradiation. The
present results suggest that a considerable amount of organic compound
s formed in extraterrestrial environments were supplied to the primiti
ve earth before the origin of life.