Synthetic, petroleum-based polymer films are extremely stable and are commo
nly used in agriculture, food packaging, fast-food restaurants, and on mili
tary and commercial ships. However, their attractive stability is counterba
lanced by two problems. One is that petroleum polymers contribute to the de
mand for expensive imported oil. The other is their great resistance to bio
degradation. When disposed they constitute a serious problem with very nega
tive environmental impact. For example, the most frequently used polyethyle
ne film takes 200 years to biodegrade. On the other hand, the use of agricu
ltural biopolymers that are easily biodegradable not only would solve these
problems but would also provide a potential new use for surplus farm produ
ction. Unfortunately, films from agricultural polymers are initially inferi
or to synthetic polymers mostly because of their difficult moldability and
poorer physicochemical properties. However, specifically modified acidic ca
rbohydrates and proteins with disulfide bondings may produce attractive alt
ernatives.