Membrane reactors have found utility in a broad range of applications inclu
ding biochemical, chemical, environmental, and petrochemical systems. The v
ariety of membrane separation processes, the novel characteristics of membr
ane structures, and the geometrical advantages offered by the membrane modu
les have been employed to enhance and assist reaction schemes to attain hig
her performance levels compared to conventional approaches. In these, membr
anes perform a wide variety of functions, oft;en more than one function in
a given context. An understanding of these various membrane functions will
be quite useful in future development and commercialization of membrane rea
ctors. This overview develops a functional perspective for membranes in a v
ariety of reaction processes. Various functions of the membranes in a react
or can be categorized according to the essential role of the membranes. The
y can be employed to introduce/separate/purify reactant(s) and products, to
provide the surface for reactions, to provide a structure for the reaction
medium, or to retain specific catalysts. Within these broad contexts, the
membranes can be catalytic/noncatalytic, polymeric/inorganic, and ionic/non
ionic and have different physical/chemical structures and geometries. The f
unctions of the membrane in a reaction can be enhanced or increased also by
the use of multiple membrane-based schemes. This overview develops a persp
ective of each membrane function in a reactor to facilitate a better apprec
iation of their role in the improvement of overall process performance.