Effect of the current intensity in the electrochemical oxidation of aqueous phenol wastes at an activated carbon and steel anode

Citation
P. Canizares et al., Effect of the current intensity in the electrochemical oxidation of aqueous phenol wastes at an activated carbon and steel anode, IND ENG RES, 38(10), 1999, pp. 3779-3785
Citations number
26
Categorie Soggetti
Chemical Engineering
Journal title
INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH
ISSN journal
08885885 → ACNP
Volume
38
Issue
10
Year of publication
1999
Pages
3779 - 3785
Database
ISI
SICI code
0888-5885(199910)38:10<3779:EOTCII>2.0.ZU;2-A
Abstract
The effect of the current intensity in the electrochemical oxidation of aqu eous phenol wastes at an activated carbon and steel anode was investigated. Results confirm that three reaction pathways were involved in the electroc hemical process: direct degradation or electrochemical cold combustion, che mical oxidation, and polymerization. The chemical oxidation pathway was the most important for the range of current intensities studied. To interpret the experimental behavior, a simple mathematical model was proposed and tes ted, obtaining good agreements between experimental and simulated data.