The development and characterization of a fracture-toughened acrylic for luting total joint arthroplasties

An autopolymerizing fracture-toughened acrylic lute was developed utilizing a toughened prepolymer and a gel-polymerization method. Samples for mechan ical and chemical characterization were molded from this material and from untoughened controls. Mechanical testing showed that the mode I fracture to ughness (K-IC) of the toughened lute was increased by 163% over that of the untoughened acrylic controls while the compressive strength and modulus we re decreased by 36% and 34%, respectively. The flexural properties of the e xperimental material were not adversely affected. Analysis of molecular wei ght and residual monomer data for the experimental and control materials de monstrated that the increase in toughness was due to the presence of the to ughened prepolymer. The use of the gel polymerization process gave excellen t homogeneity with very low porosity for the experimental polymer, but it r esulted in a significant increase in the residual monomer concentration due to the absence of a dispersed phase of prepolymer remnants. This raises qu estions concerning tissue response to the experimental system. (C) 1999 Joh n Wiley & Sons, Inc.