A unified quantal and classical description of the stereodynamics of elementary chemical reactions: State-resolved k-k(')-j(') vector correlation forthe H+D-2(v=0, j=0) reaction

We present a detailed and quantitative comparison of the quantum mechanical (QM) and quasiclassical (QCT) descriptions of the stereodynamics of elemen tary chemical reactions. Analogous formulations of the QM and QCT k-k(')-j( ') vector correlation in atom-diatom reactions have been derived and shown to be equivalent in the correspondence principle limit. The comparison betw een the results obtained from the application of the QM and QCT methodologi es to the H + D-2(upsilon = 0, j = 0)--> HD(upsilon('),j(')) + D reaction a t a collision energy of 1.29 eV renders an almost quantitative agreement. ( C) 1999 American Institute of Physics. [S0021-9606(99)00435-3].