FROM SYNTHESIS TO CHEMICAL-REACTIVITY OF SUPPORTED D(0) COMPLEXES .2.REACTIVITY OF SILICA-ANCHORED ALKYL-ZIRCONIUM COMPLEXES - AN ATTEMPT TOWARD FUNCTIONALIZATION OF ALKANES

Authors
QUIGNARD F CHOPLIN A BASSET JM
Citation
F. Quignard et al., FROM SYNTHESIS TO CHEMICAL-REACTIVITY OF SUPPORTED D(0) COMPLEXES .2.REACTIVITY OF SILICA-ANCHORED ALKYL-ZIRCONIUM COMPLEXES - AN ATTEMPT TOWARD FUNCTIONALIZATION OF ALKANES, Journal of the Chemical Society. Dalton transactions, (16), 1994, pp. 2411-2414
Citations number
37
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
16
Year of publication
1994
Pages
2411 - 2414
Database
ISI
SICI code
0300-9246(1994):16<2411:FSTCOS>2.0.ZU;2-N
Abstract
Silica-anchored alkyl zirconium complexes [Zr]s-R (R = cyclooctyl, Pr or Me) have been generated by reaction of [Zr]s-H complexes with the r elevant alkanes. Their stoichiometric reactivity towards molecules suc h as carbon monoxide and olefins was studied in order to estimate the potential of such systems to activate and functionalize alkanes cataly tically.