The deposition of AuSn solder at the eutectic composition (80 wt.% Au, 20 w
t.% Sn) on a wetted, chemically inert metallic barrier has been studied in
relation to its use in optoelectronic packaging. The bonding structure, con
sisting of a W barrier, the top part of which is doped with Ni (or Ti) to p
rovide wetting by molten AuSn, and the homogeneous 80-20 AuSn soldier sever
al micrometers thick, has been grown by the Pulsed Laser-assisted Depositio
n (PLD) technique on 2" silicon wafers. The composition of the AuSn layer w
as controlled within better than 1 wt.% as probed by EDX across the wafer d
iameter. The molten solder exhibited good wetting properties on the W modif
ied layer and the whole structure was found to be chemically stable against
thermal cycling at 320 degrees C for over 3 min. The use of molten AuSn ta
rgets makes the PLD technique a most competitive one for the achievement of
high quality and reliable AuSn solder.