SOLVENT-DEPENDENT FORMS OF LITHIATED 5,5,10,10,15,15,20,20-OCTAETHYLPORPHYRINOGEN IN SOLUTION AND IN THE SOLID-STATE AND REACTION WITH TETRAHYDROFURAN

Authors
DEANGELIS S SOLARI E FLORIANI C CHIESIVILLA A RIZZOLI C
Citation
S. Deangelis et al., SOLVENT-DEPENDENT FORMS OF LITHIATED 5,5,10,10,15,15,20,20-OCTAETHYLPORPHYRINOGEN IN SOLUTION AND IN THE SOLID-STATE AND REACTION WITH TETRAHYDROFURAN, Journal of the Chemical Society. Dalton transactions, (16), 1994, pp. 2467-2469
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
16
Year of publication
1994
Pages
2467 - 2469
Database
ISI
SICI code
0300-9246(1994):16<2467:SFOL5>2.0.ZU;2-J
Abstract
The fully lithiated form of 5,5,10,10,15,15,20,20-octaethylporphyrinog en (H-4L) synthesized in tetrahydrofuran (thf ) has been structurally characterized in its solvated form Li4L.3thf, while its unsolvated for m from n-hexane behaves as a 'superbase' capable of decomposing thf to the lithium enolate identified in the aggregate Li6L(OCH=CH2)2.4thf.