Haloacetylated enol ethers. 14 [6]. Reaction of beta-alkoxyvinyl trifluoromethyl ketones with N-methylhydroxylamine

Citation
Map. Martins et al., Haloacetylated enol ethers. 14 [6]. Reaction of beta-alkoxyvinyl trifluoromethyl ketones with N-methylhydroxylamine, J HETERO CH, 36(4), 1999, pp. 837-840
Citations number
36
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
JOURNAL OF HETEROCYCLIC CHEMISTRY
ISSN journal
0022152X → ACNP
Volume
36
Issue
4
Year of publication
1999
Pages
837 - 840
Database
ISI
SICI code
0022-152X(199907/08)36:4<837:HEE1[R>2.0.ZU;2-Y
Abstract
The reaction of a series of beta-methoxyvinyl trifluoromethyl ketones [CF3C OC(R-2) = C(OMe)R-1, where R-1 = Me, -(CH2)(3)-C3, -CH2)(4)-C3, Ph and R-2 = H, Me, -(CH2)(3)-C4, -(CH2)(4)-C4] with N-methylhydroxylamine is reported . The regiochemistry of the reaction are explained by MO calculation data.