Type c cytochromes, which are involved in the electron transport system, ar
e also able to catalyze peroxidase-like reactions in the presence of an ele
ctron acceptor, such as hydrogen peroxide or an organic hydroperoxide. This
work reviews the catalytic activity of cytochrome c, and the potential des
ign by site-directed mutagenesis and chemical modification of new biocataly
sts for environmental purposes. (C) 1999 Elsevier Science B.V. All rights r
eserved.