Properties of the L and lyotropic phases in CTAB/glycerol/water and CTAB/glyceraldehyde/water systems

Citation
Ab. Cortes et al., Properties of the L and lyotropic phases in CTAB/glycerol/water and CTAB/glyceraldehyde/water systems, LANGMUIR, 15(20), 1999, pp. 6658-6663
Citations number
24
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
LANGMUIR
ISSN journal
07437463 → ACNP
Volume
15
Issue
20
Year of publication
1999
Pages
6658 - 6663
Database
ISI
SICI code
0743-7463(19990928)15:20<6658:POTLAL>2.0.ZU;2-S
Abstract
The behavior of glycerol and glyceraldehyde as cosurfactants in the ternary CTAB/glycerol/water and CTAB/glyceraldehyde/water systems is studied. The phase diagrams only show the L and the hexagonal H-1 phases. The L phase co nductivity results at low surfactant concentration agree with no interactio n between both cosurfactants and CTAB micelles. The rheological behavior of the L phase samples shows that the micelles at low surfactant content beha ve as Newtonian fluids. Whereas, samples close to the hexagonal phase show a shear-thinning behavior, consistent with the formation of cylindrical mic elles, and in this case, there is a larger interaction between both cosurfa ctants with the CTAB micelles.