The influence of high pressure on the discontinuity of the isotropic-nematic and the isotropic-smectic A phase transitions studied by the low-frequency nonlinear dielectric effect measurements
A. Drozd-rzoska et al., The influence of high pressure on the discontinuity of the isotropic-nematic and the isotropic-smectic A phase transitions studied by the low-frequency nonlinear dielectric effect measurements, MOL CRYST A, 330, 1999, pp. 1251-1258
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS
Results are presented for isothermal, pressure studies of the low frequency
nonlinear dielectric effect in the isotropic phase of 8CB (isotropic - nem
atic (I-N) transition) and 12CB (isotropic - smectic(I-SmA transition), Thi
s made possible to determined the pressure dependence of the nematic and sm
ectic clearing temperatures as well as the extrapolated temperatures of a h
ypothetical continuous phase transition up to P = 200 MPa. Ln the case of t
he I-N transition the discontinuity of the transition (Delta T) increases s
ystematically with pressure while for the I-SmA transition Delta T decrease
s with rising pressure.