The influence of high pressure on the discontinuity of the isotropic-nematic and the isotropic-smectic A phase transitions studied by the low-frequency nonlinear dielectric effect measurements

Citation
A. Drozd-rzoska et al., The influence of high pressure on the discontinuity of the isotropic-nematic and the isotropic-smectic A phase transitions studied by the low-frequency nonlinear dielectric effect measurements, MOL CRYST A, 330, 1999, pp. 1251-1258
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS
ISSN journal
1058725X → ACNP
Volume
330
Year of publication
1999
Part
3
Pages
1251 - 1258
Database
ISI
SICI code
1058-725X(1999)330:<1251:TIOHPO>2.0.ZU;2-U
Abstract
Results are presented for isothermal, pressure studies of the low frequency nonlinear dielectric effect in the isotropic phase of 8CB (isotropic - nem atic (I-N) transition) and 12CB (isotropic - smectic(I-SmA transition), Thi s made possible to determined the pressure dependence of the nematic and sm ectic clearing temperatures as well as the extrapolated temperatures of a h ypothetical continuous phase transition up to P = 200 MPa. Ln the case of t he I-N transition the discontinuity of the transition (Delta T) increases s ystematically with pressure while for the I-SmA transition Delta T decrease s with rising pressure.