Mechanically and light induced anchoring of liquid crystal on polyimide film

Citation
M. Nishikawa et al., Mechanically and light induced anchoring of liquid crystal on polyimide film, MOL CRYST A, 329, 1999, pp. 623-630
Citations number
8
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS
ISSN journal
1058725X → ACNP
Volume
329
Year of publication
1999
Part
2
Pages
623 - 630
Database
ISI
SICI code
1058-725X(1999)329:<623:MALIAO>2.0.ZU;2-6
Abstract
The interplay between the effects of mechanical rubbing and UV light induce d deimidization on polyimide films has been studied. Exposure to depolarize d UV light of rubbing PI film was found to suppress effective anchoring ene rgy. Polarized light led to the alteration of the orientational distributio n of PI molecules obtained by rubbing i.e to the change of both anchoring e nergy and easy axis direction. A simple model based on the selective UV lig ht absorption with consequent deimidization of PI molecules describes the U V-initiated processes on the rubbed polyimide layers but contradicts the ex perimental data obtained for non-rubbed layers. The results obtained show t hat UV exposure can be effectively used to control anchoring parameters.