Zenithal anchoring angle and anchoring strength on oxidized silane plates

Citation
Jg. Fonseca et al., Zenithal anchoring angle and anchoring strength on oxidized silane plates, MOL CRYST A, 329, 1999, pp. 1209-1216
Citations number
7
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
MOLECULAR CRYSTALS AND LIQUID CRYSTALS SCIENCE AND TECHNOLOGY SECTION A-MOLECULAR CRYSTALS AND LIQUID CRYSTALS
ISSN journal
1058725X → ACNP
Volume
329
Year of publication
1999
Part
2
Pages
1209 - 1216
Database
ISI
SICI code
1058-725X(1999)329:<1209:ZAAAAS>2.0.ZU;2-D
Abstract
Silane coated surfaces are chemically modified by using the post-discharge of an oxygen and nitrogen cold plasma, to produce alignment layers. These o xidized surfaces yield uniform nematic cells, provided that they are previo usly rubbed unidirectionally. Depending on the oxygen concentration arrivin g to the sample surface, the zenithal anchoring orientation may be tuned fr om planar to homeotropic, and tilted in-between. We measure the zenithal an choring strength in the planar region, for 4-n-pentyl-4'-cyanobiphenyl (5CB ), as a function of the oxygen concentration and of temperature. The anchor ing strength is found roughly independent of the oxygen concentration, with an extrapolation length similar to 100 nm for Delta T=1.5K.