Improved efficiency of the ruthenium-catalyzed redox isomerization of allyl alcohols

Authors
Slugovc, C Ruba, E Schmid, R Kirchner, K
Citation
C. Slugovc et al., Improved efficiency of the ruthenium-catalyzed redox isomerization of allyl alcohols, ORGANOMETAL, 18(20), 1999, pp. 4230-4233
Citations number
20
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
20
Year of publication
1999
Pages
4230 - 4233
Database
ISI
SICI code
0276-7333(19990927)18:20<4230:IEOTRR>2.0.ZU;2-B
Abstract
The new complexes [RuCp(PR3)(CH3CN)(2)]PF6 (R = Ph, Me, Cy) are highly acti ve catalysts for the redox isomerization. of allyl alcohols to give the cor responding carbonyl compounds in high yields and high efficiency. ALL react ions proceed under mild reaction conditions. In some cases, allylations of the carbonyl compounds could be achieved in, a tandem catalytic process.