Reaction of bis(1-substituted-1-boratabenzene)bis-(trimethylphosphine)zirconium(II) with 1,3-diynes

Authors
Ashe, AJ Al-Ahmad, S Kampf, JW
Citation
Aj. Ashe et al., Reaction of bis(1-substituted-1-boratabenzene)bis-(trimethylphosphine)zirconium(II) with 1,3-diynes, ORGANOMETAL, 18(20), 1999, pp. 4234-4236
Citations number
37
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
ORGANOMETALLICS
ISSN journal
02767333 → ACNP
Volume
18
Issue
20
Year of publication
1999
Pages
4234 - 4236
Database
ISI
SICI code
0276-7333(19990927)18:20<4234:ROB>2.0.ZU;2-1
Abstract
1,4-Diphenyl-1,3-butadiyne readily displaces PMe3 from bis(N,N-diisopropyl- 1-amino-1-boratabenzene)bis(trimethylphosphine)zirconium(II) to afford a 1: 1 adduct which contains a 2,5-diphenyl-1-zirconacyclopenta-2,3,4-triene uni t.