Synthesis and reactions of highly sterically hindered organosilicon compounds of the type (Me3Si)(3)CSi(C6H4-OMe-p)MeX and (Me3Si)(3)CSi(C6H4-Me-p)MeX

Authors
Safa, KD Bolourtchian, M Asadi, MG
Citation
Kd. Safa et al., Synthesis and reactions of highly sterically hindered organosilicon compounds of the type (Me3Si)(3)CSi(C6H4-OMe-p)MeX and (Me3Si)(3)CSi(C6H4-Me-p)MeX, PHOSPHOR SU, 149, 1999, pp. 229-236
Citations number
11
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
149
Year of publication
1999
Pages
229 - 236
Database
ISI
SICI code
1042-6507(1999)149:<229:SAROHS>2.0.ZU;2-J
Abstract
Direct nucleophilic displacement of TsiSi(C6H4-OMe-p)MeI and TsiSi(C6H4-Me- p)MeI with nucleophiles take place. These compounds also react with electro philes such as AgOAc and AgNO3 to give rearrangment products, for example ( Me3Si)(2)C(SiMe(2)OAC)SiMe2 (C6H4-Y-p) (Y = Me, OMe). The hydrides and brom ides of these compounds were also synthesised.