A study was made of the influence of variation of physico-chemical paramete
rs of a chromating electrolyte on the properties of chromated layers (resis
tance to salt spray and color). This study was carried out using an experim
ental scheme. Black chromating layers are very frequently used for the prot
ection of galvanized steel parts in the automobile industry. Three types of
black chromating processes were investigated, ail carefully chosen: pure z
inc, zinc-cobalt and zinc-iron. These processes act differently; a drift of
the electrolytes in industry causes some fluctuations on the properties wa
nted. The development of techniques of characterization of chromate convers
ion film as far as chemical and physical properties are concerned enabled o
ptimization of the operating conditions.