Ak. Saxena et A. Ranjan, Synthesis and spectroscopic studies on some new pentafluorophenylantimony(III and V) derivatives, SYN REAC IN, 29(9), 1999, pp. 1579-1591
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
The oxidative addition reaction of (C6F5)(2)SbCl with ICl and IN3 yielded (
C6F5)(2)SbI(X)Cl (X = Cl N-3). (C6F5)(2)SbN3 and (C6F5)(2)SbCl(NCS)N-3 were
synthesized by the displacement reactions of (C6F5)(2)SbCl with NaN3 in th
e presence of 15-crown-5 or (C6F5)(2)SbI(N-3)Cl with AgNCS, respectively. T
he reaction of bis(pentafluorophenyl)antimony(V) azido derivatives with PhN
CS yielded the corresponding 1,2-cycloaddition products i.e., tetrazole-5-t
hiones. The compounds were characterised by elemental analyses, UV, IR and
F-19 NMR spectroscopic studies.