Synthesis and spectroscopic studies on some new pentafluorophenylantimony(III and V) derivatives

Authors
Saxena, AK Ranjan, A
Citation
Ak. Saxena et A. Ranjan, Synthesis and spectroscopic studies on some new pentafluorophenylantimony(III and V) derivatives, SYN REAC IN, 29(9), 1999, pp. 1579-1591
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
29
Issue
9
Year of publication
1999
Pages
1579 - 1591
Database
ISI
SICI code
0094-5714(199910)29:9<1579:SASSOS>2.0.ZU;2-E
Abstract
The oxidative addition reaction of (C6F5)(2)SbCl with ICl and IN3 yielded ( C6F5)(2)SbI(X)Cl (X = Cl N-3). (C6F5)(2)SbN3 and (C6F5)(2)SbCl(NCS)N-3 were synthesized by the displacement reactions of (C6F5)(2)SbCl with NaN3 in th e presence of 15-crown-5 or (C6F5)(2)SbI(N-3)Cl with AgNCS, respectively. T he reaction of bis(pentafluorophenyl)antimony(V) azido derivatives with PhN CS yielded the corresponding 1,2-cycloaddition products i.e., tetrazole-5-t hiones. The compounds were characterised by elemental analyses, UV, IR and F-19 NMR spectroscopic studies.