Synthesis and spectroscopic studies on some new pentafluorophenylantimony(III and V) derivatives

Citation
Ak. Saxena et A. Ranjan, Synthesis and spectroscopic studies on some new pentafluorophenylantimony(III and V) derivatives, SYN REAC IN, 29(9), 1999, pp. 1579-1591
Citations number
23
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
29
Issue
9
Year of publication
1999
Pages
1579 - 1591
Database
ISI
SICI code
0094-5714(199910)29:9<1579:SASSOS>2.0.ZU;2-E
Abstract
The oxidative addition reaction of (C6F5)(2)SbCl with ICl and IN3 yielded ( C6F5)(2)SbI(X)Cl (X = Cl N-3). (C6F5)(2)SbN3 and (C6F5)(2)SbCl(NCS)N-3 were synthesized by the displacement reactions of (C6F5)(2)SbCl with NaN3 in th e presence of 15-crown-5 or (C6F5)(2)SbI(N-3)Cl with AgNCS, respectively. T he reaction of bis(pentafluorophenyl)antimony(V) azido derivatives with PhN CS yielded the corresponding 1,2-cycloaddition products i.e., tetrazole-5-t hiones. The compounds were characterised by elemental analyses, UV, IR and F-19 NMR spectroscopic studies.