Synthesis, characterization and fluorescence of cryptates of Sm(III), Eu(III), Tb(III), Dy(III) with a hexabenzo cryptand

Authors
Dong, WK Yang, RD Yan, L
Citation
Wk. Dong et al., Synthesis, characterization and fluorescence of cryptates of Sm(III), Eu(III), Tb(III), Dy(III) with a hexabenzo cryptand, SYN REAC IN, 29(9), 1999, pp. 1631-1640
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
SYNTHESIS AND REACTIVITY IN INORGANIC AND METAL-ORGANIC CHEMISTRY
ISSN journal
00945714 → ACNP
Volume
29
Issue
9
Year of publication
1999
Pages
1631 - 1640
Database
ISI
SICI code
0094-5714(199910)29:9<1631:SCAFOC>2.0.ZU;2-L
Abstract
Four solid cryptates of a cage-type N2O6-heteroatom hexabenzo cryptand (L) with M(III) nitrates (M = Sm, Eu, Tb, Dy) have been synthesized and charact erized by IR, fluorescence spectra, TG-DTA and molar conductances. The comp osition of these cryptates was determined as M-2(NO3)(6)L . H2O, and the st ructure [M(L)(NO3)][M(NO3)(5)(H2O)] has been suggested. Some abnormalities in the fluorescence emission intensity were found for the Tb(III) and Dy(II I) cryptates.