Asymmetric allylic substitution reaction with nitrogen and oxygen nucleophiles using monodentate chiral phosphine, 9-PBN

Authors
Hamada, Y Seto, N Takayanagi, Y Nakano, T Hara, O
Citation
Y. Hamada et al., Asymmetric allylic substitution reaction with nitrogen and oxygen nucleophiles using monodentate chiral phosphine, 9-PBN, TETRAHEDR L, 40(44), 1999, pp. 7791-7794
Citations number
43
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
44
Year of publication
1999
Pages
7791 - 7794
Database
ISI
SICI code
0040-4039(19991029)40:44<7791:AASRWN>2.0.ZU;2-8
Abstract
Asymmetric allylic substitution reactions between 1,3-diphenyl-2-propenyl a cetate and various hetero nucleophiles were efficiently carried out using t he catalysts derived from the monodentate phosphine ligands, (1R, 2S, 5R, 6 S)-2,6-dimethyl-9-phenyl-9-phosphabicyc[3.3.1]nonane and its enantiomer ((- )- and (+)-9-PBNs), and palladium (0). (C) 1999 Elsevier Science Ltd. All r ights reserved.