BIS-SUBSTITUTED TETRATHIAPENTALENES - NOVEL BUILDING-BLOCKS FOR EXTENDED TETRATHIAFULVALENES AND CONDUCTING POLYMERS

Authors
MULLER H SALHI F DIVISIABLOHORN B
Citation
H. Muller et al., BIS-SUBSTITUTED TETRATHIAPENTALENES - NOVEL BUILDING-BLOCKS FOR EXTENDED TETRATHIAFULVALENES AND CONDUCTING POLYMERS, Tetrahedron letters, 38(18), 1997, pp. 3215-3218
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
38
Issue
18
Year of publication
1997
Pages
3215 - 3218
Database
ISI
SICI code
0040-4039(1997)38:18<3215:BT-NBF>2.0.ZU;2-L
Abstract
1,3,4,6-tetrathiapentalene-2,5-dione (1) reacts in a Wittig-type fashi on with aromatic/aliphatic aldehydes 2a - h upon heating in neat triet hyl phosphite to bis-substituted tetrathiapentalenes (3a - h), which c an be oligo-/polymerized oxidatively to give vinylogous TTF derivative s or highly conducting,polymeric solids (sigma(RT) = 1 S/cm), respecti vely. (C) 1997 Published by Elsevier Science Ltd.