NEW 13-AZA BACCATINS

Citation
M. Menichincheri et al., NEW 13-AZA BACCATINS, Tetrahedron letters, 38(18), 1997, pp. 3301-3304
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
38
Issue
18
Year of publication
1997
Pages
3301 - 3304
Database
ISI
SICI code
0040-4039(1997)38:18<3301:N1B>2.0.ZU;2-0
Abstract
Upon treatment of 7-triethylsilyl-10,13-dideoxy-13-imino baccatin III (2) subsequently with diazomethane and m-chloroperbenzoic acid a few n ovel derivatives, namely methylimine 3 and oximes 4 and 5, were obtain ed. Interestingly, 4 is characterized by the hydroxyl at position 14. (C) 1997 Published by Elsevier Science Ltd.