Using single crystals of binary stoichiometric Ni3Al, the orientation depen
dence of the critical resolved shear stress (CRSS) for {111}{101} slip and
the tension/compression (T/C) asymmetry were studied in the yield stress an
omaly regime. Unlike the case in ternary alloys, it was found that Schmid's
law holds and the T/C asymmetry vanishes in stoichiometric Ni3Al. This ind
icates that plastic deformation occurs according to Schmid's law in the hig
hly ordered state. Also, the Violation of Schmid's law and the T/C asymmetr
y, which were believed to be inherent to the stress anomaly so far, are con
sidered to be additional effects due to the anti-site defects or specific t
ernary elements. The results are consistent with the idea that the CRSS is
controlled by the dislocation multiplication in (111). (C) 1999 Acta Metall
urgica Inc. Published by Elsevier Science Ltd. All rights reserved.