The objective of this article is to define and validate a mathematical
model that describes the physical and biological processes occurring
in a trickle-bed air biofilter for waste gas treatment. This model con
siders a two-phase system, quasi-steady-state processes, uniform bacte
rial population, and one limiting substrate. The variation of the spec
ific surface area with bacterial growth is included in the model, and
its effect on the biofilter performance is analyzed. This analysis lea
ds to the conclusion that excessive accumulation of biomass in the rea
ctor has a negative effect on contaminant removal efficiency. To solve
this problem, excess biomass is removed via full media fluidization a
nd backwashing of the biofilter. The backwashing technique is also inc
orporated in the model as a process variable. Experimental data from t
he biodegradation of toluene in a pilot system with four packed-bed re
actors are used to validate the model. Once the model is calibrated wi
th the estimation of the unknown parameters of the system, it is used
to simulate the biofilter performance for different operating conditio
ns. Model predictions are found to be in agreement with experimental d
ata. (C) 1997 John Wiley & Sons, Inc.