Comparative study of the acidic and catalytic properties of the mesoporousmaterial H-MCM-41 and zeolite H-Y

Citation
H. Koch et al., Comparative study of the acidic and catalytic properties of the mesoporousmaterial H-MCM-41 and zeolite H-Y, CHEM ENG TE, 22(10), 1999, pp. 807-811
Citations number
19
Categorie Soggetti
Chemical Engineering
Journal title
CHEMICAL ENGINEERING & TECHNOLOGY
ISSN journal
09307516 → ACNP
Volume
22
Issue
10
Year of publication
1999
Pages
807 - 811
Database
ISI
SICI code
0930-7516(199910)22:10<807:CSOTAA>2.0.ZU;2-F
Abstract
The objective of this work is to give a comparative characterization of alu minosilicate MCM-41 and zeolite Y, in particular with respect to acidity an d catalytic properties in hydrocarbon cracking. These studies are compared to a well investigated amorphous aluminosilicate, based on the fact that th e new mesoporous MCM-41 materials are a mixture of ordered material with am orphous pore walls. Characterization of differently treated MCM-41 material s and zeolite Y for comparison by Nz sorption, XRD, TPAD (Temperature Progr ammed Ammonia Desorption) with in situ FT-IR in combination with catalytic testing by MAT (Micro Activity Test) is discussed. Combination of the characterization data and the catalytic testing gives an interesting explanation of the surface properties especially in comparison with zeolite Y.