Comment on "On the nature of patterns arising during polymerization of acrylamide in the presence of the methylene blue-sulfide-oxygen oscillating reaction" [Chem. Phys. Lett. 295 (1998) 70-74]

Authors
Citation
Af. Munster, Comment on "On the nature of patterns arising during polymerization of acrylamide in the presence of the methylene blue-sulfide-oxygen oscillating reaction" [Chem. Phys. Lett. 295 (1998) 70-74], CHEM P LETT, 311(1-2), 1999, pp. 102-104
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
CHEMICAL PHYSICS LETTERS
ISSN journal
00092614 → ACNP
Volume
311
Issue
1-2
Year of publication
1999
Pages
102 - 104
Database
ISI
SICI code
0009-2614(19990917)311:1-2<102:CO"TNO>2.0.ZU;2-F
Abstract
In their paper, the authors state that patterns emerging in the PA-MBO syst em are generated by hydrodynamic convection instead of a diffusion induced instability involving the chemistry of the nonlinear MBO reaction. In our o pinion, their findings can be explained by the use of improperly purified s ulfide in some cases and by a low concentration of oxygen in other instance s. Recent experiments and simulations performed by our group confirm our pr evious interpretation of the patterns in the PA-MBO system in terms of Turi ng structures. In particular, our work on the effects of an electrical fiel d and light on pattern formation proves the chemical origin of the patterns . (C) 1999 Elsevier Science B.V. All rights reserved.