The mechanisms responsible for the anomalous adhesive behaviour of EPDM ela
stomer have been elucidated by studying the interfacial strength of two EPD
M networks. An extremely slow diffusion could be observed and was attribute
d to the presence of the branching of EPDM macromolecules associated with a
high degree of entanglements. It was shown that diffusion is an essential
preliminary step to obtain good interfacial co-crosslinking and hence high
final adhesive strength. (C) 1999 Academie des sciences/Editions scientifiq
ues et medicales Elsevier SAS.