Synthesis and characterization of cryptates of Sc(III) and La(III) with hexabenzocryptand

Authors
Dong, WK Yang, RD Yan, L
Citation
Wk. Dong et al., Synthesis and characterization of cryptates of Sc(III) and La(III) with hexabenzocryptand, I J CHEM A, 38(9), 1999, pp. 880-883
Citations number
17
Categorie Soggetti
Chemistry
Journal title
INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY
ISSN journal
03764710 → ACNP
Volume
38
Issue
9
Year of publication
1999
Pages
880 - 883
Database
ISI
SICI code
0376-4710(199909)38:9<880:SACOCO>2.0.ZU;2-4
Abstract
Three novel solid cryptates of a cage-type N2O6-heteroatom hexabenzocryptan d (L) with RE(III) (RE =Sc, La) chlorides and lanthanum nitrate respectivel y have been synthesized and characterized by IR and H-1 NMR spectra, TG-DTA analyses and molar conductances. The composition of these cryptates has be en determined as RE2Cl6L.4H(2)O (RE =Sc, La) and La-2 (NO3)(6)L.2H(2)O.