Ligand transfer between hard and soft metal centres. Synthesis and X-ray characterisation of a new trinuclear Pd(II) dithiocarbamate Pd-3(Et2NCS2)(4)Cl-2

Authors
Sokolov, M Imoto, H Saito, T
Citation
M. Sokolov et al., Ligand transfer between hard and soft metal centres. Synthesis and X-ray characterisation of a new trinuclear Pd(II) dithiocarbamate Pd-3(Et2NCS2)(4)Cl-2, INORG CH C, 2(9), 1999, pp. 422-423
Citations number
15
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
9
Year of publication
1999
Pages
422 - 423
Database
ISI
SICI code
1387-7003(199909)2:9<422:LTBHAS>2.0.ZU;2-3
Abstract
Reaction between PdCl2(PhCN)(2) and Nb-2(mu-S-2)(2)(Et2NCS2)(4) results in a transfer of the dithiocarbamate ligand from Nb(IV) to Pd(II) and allows i solation of the new trinuclear palladium complex Pd-3(Et2NCS2)(4)Cl-2 for t he first time. The crystal structure of the complex has been determined. (C ) 1999 Published by Elsevier Science S.A. All rights reserved.