Synthesis and structure of [mu-PhP(C5Me4)(2)] [Nb(mu-NBut)Cl](2), a novel dinuclear niobium complex supported by an ansa ligand

Authors
Shin, JH Parkin, G
Citation
Jh. Shin et G. Parkin, Synthesis and structure of [mu-PhP(C5Me4)(2)] [Nb(mu-NBut)Cl](2), a novel dinuclear niobium complex supported by an ansa ligand, INORG CH C, 2(9), 1999, pp. 428-430
Citations number
27
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANIC CHEMISTRY COMMUNICATIONS
ISSN journal
13877003 → ACNP
Volume
2
Issue
9
Year of publication
1999
Pages
428 - 430
Database
ISI
SICI code
1387-7003(199909)2:9<428:SASO[[>2.0.ZU;2-T
Abstract
The niobium complex [mu-PhP(C5Me4)(2)] [Nb(mu-NBut)Cl](2) is obtained by re action of Nb(NBut)Cl-3(py)(2) with [PhP(C5Me4)(2)]Li-2. In contrast to othe r ansa-niobocene complexes, the [PhP(C5Me4)(2)] ligand in {eta-PhP(C5Me4)(2 )] [Nb(mu-NBut)Cl](2) bridges a dinuclear Nb-2 fragment. (C) 1999 Elsevier Science S.A. All rights reserved.