T. Fujima et al., Dielectric relaxation of glass-forming organic liquid in the crossover regime between normal and supercooled liquid states, JPN J A P 2, 38(9AB), 1999, pp. L1046-L1048
Focusing on the crossover regime where the system changes from a normal liq
uid to a supercooled one, we investigate the dielectric relaxation of a gla
ss-forming liquid, salol. It is found that as temperature decreases, the al
pha-process branches into two relaxation modes in the region of the crossov
er temperature T*. This suggests that the supercooled liquid consists of tw
o domains: the cooperative-rearranging domain pointed out by light scatteri
ng studies and the independently mobile one, where the relaxation time show
s a temperature dependence of the Arrhenius type with the same activation e
nergy as that of the normal liquid.