Preparation, characterization and selective reactions of novel [1,3]diazetidine-2,4-diones (uretdiones) - A new route to generate asymmetric substituted toluylenediisocyanate-derivatives
N. Risch et al., Preparation, characterization and selective reactions of novel [1,3]diazetidine-2,4-diones (uretdiones) - A new route to generate asymmetric substituted toluylenediisocyanate-derivatives, J PRAK CH C, 341(7), 1999, pp. 616-619
The selective cyclodimerization of monomeric diisocyanates like IPDI 4 and
TDI 5 yields [1,3]diazetidine-2,4-diones (uretdiones). On this basis, a new
method for the selective transformation of the NCO-groups of asymmetric su
bstituted diisocyanates is described. The reaction with different nucleophi
les yields carbamates and ureas such as 9-11.