Derivation of infinite-slit-smeared small-angle scattering from porous surface and porous mass fractals

Citation
Pj. Mcmahon et Sd. Moss, Derivation of infinite-slit-smeared small-angle scattering from porous surface and porous mass fractals, J APPL CRYS, 32, 1999, pp. 956-962
Citations number
20
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF APPLIED CRYSTALLOGRAPHY
ISSN journal
00218898 → ACNP
Volume
32
Year of publication
1999
Part
5
Pages
956 - 962
Database
ISI
SICI code
0021-8898(19991001)32:<956:DOISSF>2.0.ZU;2-C
Abstract
Small-angle X-ray scattering (SAXS) is often used to study porous and aggre gated fractal materials. Typically when q is small or when large primary-be am intensities are required, the small-angle geometry employed introduces i nfinite-slit-height smearing into the experimental data. Herein, simple der ivations for infinite-slit-height-smeared SAXS from porous surface and mass fractals are presented, including an approximation for aggregated mass fra ctals, The models allow rapid analysis of background-subtracted data withou t the need for deconvolution. An equation is derived that allows analysis o f normalization from deconvolution routines applied to porous-fractal data. This model is tested using simulated and experimental SAXS data.