Structure of Ru(acac)(2)(ethoxide)(ethanol)center dot(1/2) trans-stilbene:Intermediate species linked by hydrogen bonds

Authors
Melendez, E Guzei, I Rheingold, AL
Citation
E. Melendez et al., Structure of Ru(acac)(2)(ethoxide)(ethanol)center dot(1/2) trans-stilbene:Intermediate species linked by hydrogen bonds, J CHEM CRYS, 29(4), 1999, pp. 399-402
Citations number
7
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542 → ACNP
Volume
29
Issue
4
Year of publication
1999
Pages
399 - 402
Database
ISI
SICI code
1074-1542(199904)29:4<399:SORDT>2.0.ZU;2-O
Abstract
The reaction of Ru(acac)(3) in ethanol in the presence of zinc and trans-st ilbene affords Ru(acac)(2)(EtO)(EtOH) complex, co-crystallized with a half- molecule of trans-stilbene as a by-product, 1. The complex crystallizes in the monoclinic space group P2(1)/n with a = 12.288 (3), b = 28.420(6), c = 13.285; (3) Angstrom, beta = 95.63(3)degrees and Z = 8. The complex exhibit s hydrogen bonds between the two Ru(acac)(2)(EtO)(EtOH) molecules.