Synthesis and crystal structure of 1-(4-bromobenzyl)-4-methyl-2,6,7-trioxabicyclo[2.2.2]octane

Authors
Loiten, MS Glogard, C Klaveness, J Fjaertoft, B
Citation
Ms. Loiten et al., Synthesis and crystal structure of 1-(4-bromobenzyl)-4-methyl-2,6,7-trioxabicyclo[2.2.2]octane, J CHEM CRYS, 29(4), 1999, pp. 493-496
Citations number
11
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
ISSN journal
10741542 → ACNP
Volume
29
Issue
4
Year of publication
1999
Pages
493 - 496
Database
ISI
SICI code
1074-1542(199904)29:4<493:SACSO1>2.0.ZU;2-9
Abstract
1-(4-Bromobenzyl)-4-methyl-2,6,7-trioxabicyclo[2.2.2]octane, C13H15BrO3, ha s been synthesized from 4-bromophenylacetic acid chloride via the oxetan es ter (3-methyl-3-oxetanyl)-methyl-2-(4-bromophenyl)acetate. The crystal stru cture of the title compound has been determined at low temperature (120 K), by X-ray diffraction methods. This compound crystallizes in the monoclinic space group P2(1)/n (No. 14), Z = 4, with lattice parameters a = 6.019(5), b = 20.990(5), c = 9.915(2) Angstrom, and beta = 101.29(1)degrees.