Phase diagram of the four-dimensional Lennard-Jones fluid

Citation
M. Hloucha et Si. Sandler, Phase diagram of the four-dimensional Lennard-Jones fluid, J CHEM PHYS, 111(17), 1999, pp. 8043-8047
Citations number
13
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
JOURNAL OF CHEMICAL PHYSICS
ISSN journal
00219606 → ACNP
Volume
111
Issue
17
Year of publication
1999
Pages
8043 - 8047
Database
ISI
SICI code
0021-9606(19991101)111:17<8043:PDOTFL>2.0.ZU;2-B
Abstract
We have used the Gibbs ensemble Monte Carlo method to investigate fluids in the N dimensional space. We consider the practical way to perform these si mulations and give expressions for the long-range corrections. Results for the four-dimensional Lennard-Jones fluid are presented. The calculated phas e diagram and several thermodynamic properties for this fluid are given. Es timates of the critical point and the critical exponent are obtained from t he phase diagram. The simulations were performed with two different simulat ion techniques: random choice and a fixed sequence of Monte Carlo steps. (C ) 1999 American Institute of Physics. [S0021-9606(99)52041-2].