M. Bjorling et al., On the application of Flory-Huggins and integral equation theories to asymmetric hard sphere mixtures, J CHEM PHYS, 111(15), 1999, pp. 6884-6889
Flory-Huggins (FH) and integral equation theories (IETs) are used to descri
be the equation of state and the relevant mixing properties of hard sphere
binary mixtures in the limit of high size-asymmetry. The results are compar
ed with those obtained from the heuristic equation of state of Mansoori (BM
CSL) [J. Chem. Phys. 54, 1523 (1971)] and with the Flory-Huggins scheme of
other authors. By choosing a physical recipe for the volume fractions of th
e two species in the mixture FH theory is shown to be a good approximation
to the entropy and the Gibbs free energy of mixing, which shows improvement
at high size-asymmetry. In addition, the results of the IETs are found to
be in overall quantitative agreement with BMCSL. The implications of our st
udy concerning colloidal systems are discussed. (C) 1999 American Institute
of Physics. [S0021-9606(99)50739-3].