Shear-induced optical anisotropy in a Langmuir monolayer: A Brewster anglereflectivity study

Shearing an initially isotropic Langmuir film by a rotating disk can lead t o an optical anisotropy at the interface. This induced anisotropy is relate d to a local in-plane molecular alignment due to the shearing and was exper imentally observed using a monolayer based on a liquid crystal polyacrylate . The variation of the anisotropy versus shearing was modelized and measure d by Brewster angle microscopy. The results reveal that the optical propert y of such a monolayer is similar to that of a two dimensional nematic liqui d crystal. (C) 1999 American Institute of Physics. [S0021-9606(99)71639-9].