Control of the regioselectivity in the Pauson-Khand reaction of 7-oxanorbornene derivatives

Authors
Arjona, O Csaky, AG Murcia, MC Plumet, J
Citation
O. Arjona et al., Control of the regioselectivity in the Pauson-Khand reaction of 7-oxanorbornene derivatives, J ORG CHEM, 64(20), 1999, pp. 7338-7341
Citations number
18
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
JOURNAL OF ORGANIC CHEMISTRY
ISSN journal
00223263 → ACNP
Volume
64
Issue
20
Year of publication
1999
Pages
7338 - 7341
Database
ISI
SICI code
0022-3263(19991001)64:20<7338:COTRIT>2.0.ZU;2-Z
Abstract
The regiochemistry of the Pauson-Khand reaction of 7-oxanorbornene derivati ves can be influenced by a remote substituent at carbon C-2. Furthermore, a remarkable effect on the regiochemical outcome of this reaction was observ ed by halide substituents in the olefin carbons, which may be utilized as a n element of control of regioselectivity.