Two-photon spectroscopy of samarium(III) in the elpasolite Cs2NaYCl6 : Sm3+

Authors
Thorne, JRG Karunathilake, A Choi, H Denning, RG Luxbacher, T
Citation
Jrg. Thorne et al., Two-photon spectroscopy of samarium(III) in the elpasolite Cs2NaYCl6 : Sm3+, J PHYS-COND, 11(40), 1999, pp. 7867-7879
Citations number
16
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
JOURNAL OF PHYSICS-CONDENSED MATTER
ISSN journal
09538984 → ACNP
Volume
11
Issue
40
Year of publication
1999
Pages
7867 - 7879
Database
ISI
SICI code
0953-8984(19991011)11:40<7867:TSOSIT>2.0.ZU;2-M
Abstract
We present polarized two-photon excitation (TPE) spectra for samarium(III) f(5) in the elpasolite Cs2NaYCI6. Approximately 80 levels have been assigne d up to 29 000 cm(-1) with the aid of a one-electron crystal field Hamilton ian, representing the most complete and extensive data set so far reported for Sm(III) at a cubic site. Deviations from the predictions of one-electro n theory are discussed in terms of the spin correlated crystal held (SCCF).