Syntheses and crystal structures of lithium and niobium complexes containing a new type of monoanionic "scorpionate" ligand

Authors
Otero, A Fernandez-Baeza, J Tejeda, J Antinolo, A Carrillo-Hermosilla, F Diez-Barra, E Lara-Sanchez, A Fernandez-Lopez, M Lanfranchi, M Pellinghelli, MA
Citation
A. Otero et al., Syntheses and crystal structures of lithium and niobium complexes containing a new type of monoanionic "scorpionate" ligand, J CHEM S DA, (20), 1999, pp. 3537-3539
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS
ISSN journal
03009246 → ACNP
Issue
20
Year of publication
1999
Pages
3537 - 3539
Database
ISI
SICI code
0300-9246(1999):20<3537:SACSOL>2.0.ZU;2-3
Abstract
The synthesis of a novel lithium compound [{Li(H2O)(bdmpza)}(4)] [bdmpza = bis(3,5-dimethylpyrazol-1-yl)acetate], containing a new "scorpionate" ligan d, and its reaction with a niobium complex to give [NbCl3(bdmpza)(PhC=CMe)] have been reported.