Crystal-field splitting and the on-site Coulomb energy of LaxSr1-xTiO3 from resonant soft-x-ray emission spectroscopy

Authors
Higuchi, T Tsukamoto, T Watanabe, M Grush, MM Callcott, TA Perera, RC Ederer, DL Tokura, Y Harada, Y Tezuka, Y Shin, S
Citation
T. Higuchi et al., Crystal-field splitting and the on-site Coulomb energy of LaxSr1-xTiO3 from resonant soft-x-ray emission spectroscopy, PHYS REV B, 60(11), 1999, pp. 7711-7714
Citations number
25
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
PHYSICAL REVIEW B-CONDENSED MATTER
ISSN journal
01631829 → ACNP
Volume
60
Issue
11
Year of publication
1999
Pages
7711 - 7714
Database
ISI
SICI code
0163-1829(19990915)60:11<7711:CSATOC>2.0.ZU;2-C
Abstract
Resonant soft-x-ray emission spectroscopy was measured on LaxSr1-xTiO3 (x = 0, 0.05, 0.10) in the Ti 2p energy region. At the Raman scattering of the e(g) resonance, the d-d transition whose Raman shift has an energy value of about 2.3 eV corresponds to the crystal-field splitting. On the other hand , at the t(2g) resonance, the d-d transition whose Raman shift is about 2.2 eV is thought to be the transition reflecting half intra-atomic Coulomb en ergy. [S0163-1829(99)01232-1].