Diffusion phenomena in hydrogenated amorphous silicon (a-Si:H) are modeled
assuming that mobile H excited from Si-H bonds normally annihilates at dang
ling-bond defects, as in the "H collision" model of light-induced metastabi
lity. This diffusion model explains the long-standing puzzle of the doping
dependence of the hydrogen diffusion coefficient DH It also yields the magn
itudes of the DH Arrhenius prefactors in doped and undoped a-Si:H. Mobile H
diffuses over an energy barrier of about 0.3 eV; at room temperature, its
diffusion rate is slightly greater than that of H in crystalline Si. [S0163
-1829(99)02536-9].